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Unit-I (07 Hours)
Classification, Nomenclature, and Isomerism
- Classification of organic compounds
- Common and IUPAC systems of nomenclature of organic compounds (up to 10 carbons, open chain, and carbocyclic compounds)
- Structural isomerism in organic compounds
Unit-II (10 Hours)
Alkanes, Alkenes, and Conjugated Dienes
Alkanes
- sp³ hybridization in alkanes
- Halogenation of alkanes
- Uses of paraffins
Alkenes
- Stability of alkenes
- sp² hybridization in alkenes
- E1 and E2 reactions:
- Kinetics and order of reactivity of alkyl halides
- Rearrangement of carbocations
- Saytzeff’s orientation and evidences
- E1 vs E2 reactions and factors affecting them
- Electrophilic addition reactions of alkenes:
- Ozonolysis
- Markownikoff’s orientation
- Free radical addition reactions of alkenes
- Anti-Markownikoff’s orientation
Conjugated Dienes
- Stability of conjugated dienes
- Diels-Alder reaction
- Electrophilic addition and free radical addition reactions
- Allylic rearrangement
Unit-III (10 Hours)
Alkyl Halides
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- SN1 and SN2 reactions:
- Kinetics and order of reactivity of alkyl halides
- Stereochemistry and rearrangement of carbocations
- SN1 vs SN2 reactions and factors affecting them
- Structure and uses of:
- Ethyl chloride, chloroform, trichloroethylene, tetrachloroethylene, dichloromethane, tetrachloromethane, and iodoform
Alcohols
- Qualitative tests for alcohols
- Structure and uses of:
- Ethyl alcohol, methyl alcohol, chlorobutanol, cetosteryl alcohol, benzyl alcohol, glycerol, and propylene glycol
Unit-IV (10 Hours)
Carbonyl Compounds (Aldehydes and Ketones)
- Nucleophilic addition reactions
- Electromeric effect
- Condensation reactions:
- Aldol condensation and crossed aldol condensation
- Cannizzaro reaction and crossed Cannizzaro reaction
- Benzoin condensation and Perkin condensation
- Qualitative tests for aldehydes and ketones
- Structure and uses of:
- Formaldehyde, paraldehyde, acetone, chloral hydrate, hexamine, benzaldehyde, vanillin, and cinnamaldehyde
Unit-V (08 Hours)
Carboxylic Acids
- Acidity of carboxylic acids
- Effect of substituents on acidity and inductive effects
- Qualitative tests for carboxylic acids, amides, and esters
- Structure and uses of:
- Acetic acid, lactic acid, tartaric acid, citric acid, succinic acid, oxalic acid, salicylic acid, benzoic acid, benzyl benzoate, dimethyl phthalate, methyl salicylate, and acetylsalicylic acid
Aliphatic Amines
- Basicity and the effect of substituents on basicity
- Qualitative tests for aliphatic amines
- Structure and uses of:
- Ethanolamine, ethylenediamine, and amphetamine
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